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Processing Conditions of Alkylation of Thiophene with Laurylene over USY Zeolite
Jin Cong, Shen Jian
Abstract
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384
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(1938KB)(
205
)
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atalytic alkylation of thiophene with laurylene by four kinds of Y zeolite catalyst was evaluated with gasoline as raw material in a small batch reactor. The experimental results show that USY1 molecular sieve shows highest alkylation activity and better selectivity than the other three catalysts. The optimum conditions of catalytic alkylation by USY1 molecular sieve was as follows: the reaction temperature 140 ℃, reaction time 2 h, catalyst to oil ratio 1∶10. Under above conditions, thiophene conversion rate could reach 88.17%, and high activity could be kept after recycling the catalyst 4 times.
2014, 34 (2): 29-32.
DOI:
10.3696/j.issn.1672-6952.2014.02.008
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atalytic Oxidative Desulfurization from FCC Gasoline by Niobium Modified SBA15
RUAN Benxi, SHEN Jian, LI Shaokai, NIE Ning
Abstract
(
310
)
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(2239KB)(
227
)
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Niobium Modified SBA15 was synthesized by the wetness impregnation with niobic acid as precursor. The desulfurization of FCC gasoline was carried out with the mass fraction of 30% H2O2 as the oxidant, NbSBA15 as the catalyst, and N, Ndimethyl formamide(DMF) as the extractant. The sulfur removal rate and yield of FCC gasoline can reach 95.4% and 83.8% under the following conditions: reaction temperature: 60 ℃, reaction time: 60 min, weight ratio of catalyst/FCC gasoline: 5%, mole. ratio of oxidant/sulphur compounds 3∶1, and volume ratio of solvent (DMF) to oil was 10.
2013, 33 (3): 24-27.
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Adsorption Removal of Basic Nitrogen in the Shale Diesel by USY Molecular Sieve
LI Shaokai, LI Linlu, SHEN Jian, RUAN Benxi
Abstract
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459
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167
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Adsorption removal of basic nitrogen compounds in the shale diesel with USY molecular sieves was investigated. The effect of adsorption time, temperature and adsorbent/oil weight ratio on the nitrogen removal rate was studied, and found that highest nitrogen removal rate (30.73%) are obtained under the following conditions: the adsorbent to oil weight ratio of 0.03, the adsorption temperature of 120 ℃, the adsorption time of 30 min. Simultaneously, the static equilibrium adsorption capacity can reach 27.2 mg/g. After regenerated for several cycles, the removal rate of basic nitrogen compounds is still more than 25%. Adsorption kinetics suggested that adsorption denitrogenation follows the second-order equation.
2013, 33 (1): 22-24.
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Catalytic Oxidation of Styrene over Vanadium Modified SBA15
YIN Wenxiang, SHEN Jian
Abstract
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493
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259
)
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Vanadium complexes modified mesoporous molecular catalysts were prepared by impregnation and hydrothermal method respectively, and then characterized by XRD,N2 adsorptiondesorption(BET) and FTIR techniques. The results show that both the catalyst samples with impregnation and hydrothermal methods kept mesoporous structure well and vanadium oxide were dispersed uniformly in mesoporous materials. The catalytic performance was evaluated by the oxidation styrene to benzaldehyde, and found that the conversion can reach 76.3%, and selectively to benzaldehyde is 86.7% under optimum conditions.
2013, 33 (1): 12-15.
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Adsorption Desulfurization With Nb/SBA-15 Molecular Sieve
ZHAO Ming-fei, SHEN Jian, WANG Lei, NIE Ning, LI Shao-kai
Abstract
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409
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312
)
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Niobic acid/SBA-15 molecular sieve was prepared by impregnation method, and characterized by XRD and BET. The results show specific surface area, pore volume and pore diameters of the sample slightly decreased; however, mesoporous structure was well preserved. Its desulfurization performance from model oil was studied by static adsorption method. The results show that the sulfur removal rate can reach 31.30% and saturation adsorption capacity was 599 μg/g under the following optimum conditions: niobic acid/support 10wt%, adsorption temperature 120 ℃, time 30 min and catalyst/oil weight ratio 1∶20.
2012, 32 (4): 17-20.
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Removal of Basic Nitrogen Compounds FromOil by Adsorption With RE/Y Zeolite
ZHU Jin-zhu, FENG Rui-jiang, SHEN Jian
Abstract
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368
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189
)
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The removal of basic nitrogen compounds from model oil (consisting of quinoline and dodecane as solvent) over Rare-earth-metal-based Y molecular sieve as adsorbent in batch-wise reactor. The optimum adsorption temperature was tested and thermodynamics and kinetics of adsorption were investigated. The results showed that the optimum adsorption temperature was 393K,the nitrogen removal can reach 55.8%, and statically saturated adsorption capacity was 23.56 mg/g. The adsorption process over RE/Y zeolite was agreed well with the Langmuir model and pseudo-second-order rate model, and was an endothermic chemisorption which run spontaneously, the activation energy was 11.49 kJ/mol.
2012, 32 (2): 12-15.
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Nb Modified SBA-15 Mesoporous Molecular Sieve Catalytic Synthesis of Isoproyl Oleate
WEI Tian-sheng,SHEN Jian
Abstract
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395
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(246KB)(
168
)
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Nb-SBA-15 mesoporous molecular sieve was synthesized in the co-impregnation method. The sample was characterized by XRD and BET, showing: Nb-SBA-15 melecular sieve had still highly ordered two-diemensional hexagonal mesoporous structure. The investigation on Nb-SBA-15 synthesis of isoproyl oleic shows that the mass fraction of Nb is 15%, molar ratio of alcohol and oleic acid is 2.5∶1,reaction temperature is 170 ℃,reaction time is 4 h, the yield of isoproyl oleic is up to 64.24%.
2009, 29 (3): 26-29.
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Catalytic Synthesis of Methyl Oleate by Mesoporous Sieve Nb2O5/SBA-15
LI Chun-jing, SHEN Jian, ZHANG Liang, WANG Chao
Abstract
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281
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264
)
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Nb2O5/SBA-15 catalyst was prepared by impregnation with mesoporous molecular sieve SBA-15 as the carrier, and characterized by XRD, BET and other methods. The results show that catalyst Nb2O5/SBA-15, a highly ordered two-dimensional hexagonal mesoporous structure,has larger specific surface area,pore size and pore volume. The catalytic capability of Nb2O5/SBA-15 was studied for esterification, and the optimum reaction conditions were found as follows:n(methanol)/n(oleic acid)=2∶1,reaction temperature 160 ℃,reaction time 4 h,ratio of catalyst to reaction 9.10%. Better reuse ability of Nb2O5/SBA-15 can be also obtained, which confirms Nb2O5/SBA-15 a suitable catalyst for the esterification.
2008, 28 (4): 9-12.
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Kinetics of Synthesis of ETBE Over Mesoporous Molecular Sieve Catalys t SBA -15 -HSO
3
ZHAO Xin, SHEN Jian, JIAO Ho ng -yu
Abstract
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307
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324
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Well-ordered meso porous organic -inorganic hybrid SBA-15- HSO
3
containing alkyl(methy1)and sulfonic acid groups was directly synthesized via hydro the rmaltechnique and characterized by XRD and nitrogen adsorption.The results show that catalyst SBA -15- HSO
3
, a highly ordered two -dimensional hexagonal me so porous structure , has greater specific surface area , pore size and pore volume .Ethyl tertiary -butyl ether (ETBE)was synthesized by the reaction of ethyl alcohol and tertiary butyl alcohol with SBA -15 -HSO
3
as a catalyst , and the reaction dynamics model had been established.The reaction process carries on in the steel sealed rhythmic reaction cauldron without the influence of internal and external diffusion.The etherification reaction kinetic experiment data could be obtained with the change of the raw material density and the reaction temperature , then such a kinetic model r=kC
1.5
A
C
-0.5
B
, would be obtained, finally got the frequency factor 1 .3 ×10
7
h
-1
and activation energy 52.86kJ/mo l.At the same time , a theoretica1 mode1 r=k′C
1.5
A
C
-0.5
B
would be obtained according to the reaction mechanism , with frequency factor 1 .2 ×10
7
h
-1
and activation energy 52 .56kJ/mol .So the surface reaction could be considered as the rate -determining step.
2007, 27 (4): 27-30.
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Catalytic Synthesis of Tetradecylbenzene With Supported HF/USY Catalyst
LIU Chuan -bin,WANG Yue -mei,SHEN Jian
Abstract
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345
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341
)
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Tetradecy lbenzene was prepared by the alkylation of benzene with tetradecene over supported hydrofluoric acid on USY. The catalytic performances of the catalysts were investigated by alkylation reaction of benzene and tetradecene in a liquid fixed micro -reactor .The influences of reaction temperature, calcination temperature , space velocity and the composition of the catalysts on the catalytic performances were studied .Then the catalyst stability performance was also studied.The results show that the conversion of tetradecene is 98 .54 % and selectivity of 2-tetradecylbenzene is 52 .68 % under the conditions of 6.0 %mass fraction of fluorine , 300 ℃ calcinations temperature , 140 ℃ reaction temperature , 3 .0 h
-1
space velocity(WHSV), and 10∶1 of mole ratio of benzene and tetradecene .HF/ USY catalysts have highly activity and stability .
2006, 26 (2): 34-37.
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Production of Heavy Traf fic Paving Asphalt by Blending FCC Slurry in Propane Deasphalted Asphalt
ZHANG De -hua,SHEN Jian,et al
Abstract
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404
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185
)
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The experiment of producing heavy traffic paving asphalt was carried out with the FCC slurry and the propane deasphalted asphalt as the feedstock by uniform prescription design method .The experiment scheme was designed by original FCC slurry , above 400 ℃ slurry , above 445 ℃ slurry , and propane deasphlted asphalt as fact rs.The mathematic model of blending composition and asphalt w as set up by gradual regression of the experiment date , the effect of the blending composition on the asphalt was reflected quantified , and the optimal composition(above 400 ℃ slurry)which blended in proane deasphalt was found .Using FCC slurry as modified solvent not only makes full use of the slurry , but also improves the property of propane deasphalted asphalt .Based on mathematic model , the predicted results conformed with the measured results by using uniform prescription design of blending asphalt .The heavy traffic paving asphalt can be produced according with national standard of heavy traffic paving asphalt .It can be used as a basis for industrialization.
2005, 25 (3): 28-31.